Morphology, thermomechanical properties, and biodegradability of low density polyethylene/starch blends

Author(s):  
I. M. Thakore ◽  
Srividya Iyer ◽  
Anjana Desai ◽  
Ashish Lele ◽  
Surekha Devi
Author(s):  
Norshahida SARIFUDDIN ◽  
Mohammad Anuar Zaki SHAARI ◽  
Nur’ Aishah AHMAD SHAHRIM ◽  
Ahmad Zahirani AHMAD AZHAR ◽  
Hafizah Hanim MOHD ZAKI

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Emad S. Shafik ◽  
Azza A. Ward ◽  
Adel Farid Younan

Purpose This study aims to develop a biodegradable linear low-density polyethylene (LLDPE)/starch blends with improved mechanical and flow characteristics and evaluate the probability of using essential oils such as Moringa oleifira and castor oils as green plasticizers and compatibilizers to avoid using harmful chemicals. Design/methodology/approach Corn starch was blended with LLDPE through the melt blending technique. The corn starch content was varied from 5 to 40 phr in LLDPE. To enhance poor mechanical characteristic of the LLDPE/starch, essential oils such as M. oleifira and castor oils were incorporated into the composites with different concentrations starting from 1 to 7 phr. The essential oils’ effect on mechanical, flow character, thermal stability and electrical properties of the LLDPE/starch was also investigated. The morphology of LLDPE/starch containing essential oils was also investigated by scanning electron microscope (SEM). Findings The results revealed that increasing the corn starch content had an adverse effect on mechanical and flow characteristics of the composites, whereas incorporation of essential oils had increased the flow and mechanical characteristics of the composites. Also, dielectric measurements revealed that permittivity and dielectric loss increased by increasing oil content. Moreover, the values of the blends containing castor oil are higher compared to that containing M. oleifira. The SEM micrographs illustrated that the presence of essential oils in LLDPE/starch enhanced the distribution and the homogeneity of the composites, and the particle size of starch granules became smaller in LLDPE matrix. Originality/value This study aims to introduce green plasticizer and compatibilizer to avoid using harmful chemicals in packaging industry.


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